Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) dichloride dihydrate
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چکیده
منابع مشابه
Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) dichloride dihydrate
In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol-ecules are linked into a th...
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The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa-hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O-H⋯O hydrogen bonds.
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The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,2':6',2''-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, maki...
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In the title hydrated mol-ecular salt, C12H14N2S2 (2+)·2Cl(-)·2H2O, the dihedral angle between the benzene rings in the dication is 9.03 (17)° and the C-S-S-C torsion angle is 96.8 (2)°. The crystal packing can be described as alternating organic and anionic water layers lying parallel to (100), which are linked by N-H⋯Cl and N-H⋯O hydrogen bonds. O-H⋯Cl hydrogen bonds and aromatic π-π stacking...
متن کامل1,4,8,11-Tetraazoniacyclotetradecane diaquatetrachloridomanganese(II) dichloride dihydrate
The title compound, (C(10)H(28)N(4))[MnCl(4)(H(2)O)(2)]Cl(2)·2H(2)O, consists of isolated octa-hedral [MnCl(4)(H(2)O)(2)](2-) anions, tetra-protonated 1,4,8,11-tetra-azoniacyclo-tetradecane cations, chloride anions and water mol-ecules connected by a network of hydrogen bonds. The Mn(II) atom is situated on an inversion centre, and the 1,4,8,11-tetra-azoniacyclo-tetradecane cation is located on...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812021459